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Via Giuba, 11 20132 Milano Tel. 02 28314410 - Fax 02 2871777 |
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| Lithium Triborate – LBO |
LBO is a nonlinear optical crystal with combination of number of unique features:
LBO is perfectly suitable for various nonlinear optical applications:
EKSMA offers:
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![]() SHG tuning curves of LBO |
![]() NCPM SHG temperature dependance of LBO |
| Beta Barium Borate – BBO |
BBO is a nonlinear optical crystal with combination of number of unique features:
As a result of its excellent properties BBO has a number of advantages for different applications:
EKSMA offers:
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![]() SHG tuning curve of BBO |
![]() OPO tuning curves of BBO at 355 nm pump |
| Potassium Titanyl Phosphate – KTP |
KTP (KTiOPO4) is a nonlinear optical crystal, with excellent nonlinear, electrooptical and acoustooptical properties. A combination of high nonlinear coefficient, wide transparency range, and broad angular as well as thermal acceptances makes KTP very attractive for different nonlinear optical and wavequide applications. EKSMA offers different kinds of KTP crystals depending on required application: KTP for extracavity systems (Ex-KTP), KTP for Intracavity (In-KTP) and KTP with High Gray Tracking Resistivity (HGTR KTP). Ex-KTP is standard crystal with the parameters mostly used in extracavity configuration when the single pass through the crystal is required. In-KTP crystals are optimised for SHG intracavity confi-guration in low peak power CW lasers. Because of large number of passes through the crystal low insertion losses and high homogeneity are essential for crystal efficiency. The special highest quality material selected by SHG efficiency mapping of each crystal, fine surface polishing and dual band AR coatings with very low losses allow EKSMA to produce KTP crystals suitable for infracavity SHG application. HGTR KTP is the new crystal type grown by special recently implemented technology. It has almost 2 times larger damage and gray tracking thresholds allowing to use HGTR KTP in high power lasers. Transparency band edges of KTP crystal are at 0.35 µm in UV and at 3.5 µm in IR region. The phase-matching range of KTP crystal lies in 0.99–3.3 µm region. This allows to use KTP as intracavity and extracavity frequency doubler for the most commonly used lasers, such as Nd:YAG, Nd:YVO and Nd:YLF(1). Fig. 1 represents Type 2 SHG tuning curve of KTP in x-y plane. In x-y plane the slope ∂ (∆k)/ ∂θ is small. This corresponds to quasi-angular noncritical phase-matching, which ensures the double advantage of a large acceptance angle and a small walk off. Otherwise in x-z plane the slope ∂ (∆k)/ ∂λ is almost zero for wavelengths in the range 1.5–2.5 µm and this corresponds to quasi-wavelength noncritical phase-matching, which ensures a large spectral acceptance. Wavelength noncritical phase-matching is highly desirable for frequency conversion of short pulses. As a lasing material for OPG, OPA or OPO, KTP can most usefully be pumped by Nd lasers and their second harmonic or any other source with intermediate wavelength, such as a dye laser (near 600 nm). EKSMA offers:
EKSMA guarantees:
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![]() Fig. 1. Type 2 SHG in x-y plane |
![]() Fig. 2. Type 2 SHG in x-z plane |
![]() Fig. 3. OPO tuning curve in x-y plane |
![]() Fig. 4. OPO tuning curve in x-z plane |
| Potassium Dideuterium Phosphate and its Isomorphs - KD*P |
Custom manufacturing capabilities:
Applications:
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![]() DKDP Second harmonic generation phasematching |
![]() KDP Second harmonic generation phasematching |
| Lithium Iodate – LiIO3 | ||||||||||||
Applications
EKSMA offers:
Standard product specifications:
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![]() LiIO3 Second harmonic generation phasematching |
| Ultrathin Crystals for Femtosecond Applications | ||||||||||||||||||||||||||||||||||||||||||||
Thin crystals for ultrashort pulse applications are available from EKSMA Co. Optimal thickness nonlinear crystals are used for:
The crystals of thickness down to 100 µm can be prepared as free standing crystals (not attached on any kind of support). However the ring mounts are highly recommended for the safe handling of these thin crystals. The tolerance is ±50 µm for crystals of thickness down to 300 µm and ±20 µm for crystals of thickness down to 100 µm. Free standing crystals:
* the thickness should be about 2 mm for max aperture KDP and LiIO3. BBO, LBO and KDP crystals of thickness less than 100 µm can be supplied optically contacted on UV Fused Silica substrates sizes 10×10×2 mm or 12×12×2 mm. Other sizes of substrates are also available on request. The tolerances of BBO and LBO crystal thickness are +10/-5 µm, for KDP and LiIO3 ±10 µm. Optically contacted crystals:
EKSMA Co. provides various AR, BBAR and protective coatings for all free standing crystals. The coatings are not available for optically contacted crystals. Ring mounts made from anodized aluminium are available for the safe and convenient handling of ultrathin crystals. The standard sizes are dia 1” and 25 or 30 mm. The thickness of mount is 10 mm. Custom shape and size mounts are available too. |
| Infrared Nonlinear Crystals - AgGaS2, AgGaSe2, GaSe, ZnGeP2 |
Optical nonlinear crystals like ZnGeP2, AgGaSe2, AgGaS2, GaSe, Tl3AsSe3 have gained tremendous interest for the middle and deep infrared applications due to their unique features. The crystals have large effective optical nonlinearity, wide spectral and angular acceptance, broad transparency range, noncritical requirements for temperature stabilisation and vibration control, are well mechanically processed (except of GaSe and Tl3AsSe3). ZnGeP2 has band edges at 0.74 and 12 µm. Its useful transmission range lies from 2.1 to 10.6 µm with absoprtion α lower than 0.04 cm-1. ZnGeP2 has the largest nonlinear optical coefficient and relatively high laser damage threshold. It was successfully used in the following applications: up-conversion of CO2 laser light to near IR range(1) via mixing with 1.06 mm; sum frequency generation of CO and CO2 laser radiation(2); efficient SHG of pulsed CO(3), CO2(4) (49% efficiency at 1 GW/cm2 intensity of 2 ns pulses, 9.52 mm wavelength) and chemical DF-laser(5), OPO light generation in mid infrared when pumped by erbium(6,7) and holmium(8) lasers. AgGaSe2(9) has band edges at 0.73 and 18 µm. Its useful transmission range lying within 0.9–16 µm and wide phase matchability provide excellent potential for OPO applications when pumped by variety of currently available lasers. Tuning within 2.5–12 µm was obtained when pumped by Ho:YLF laser at 2.05 µm(10); NCPM operation within 1.9–5.5 µm was achieved(11) pumping at 1.4–1.55 µm. Efficient SHG of pulsed CO2 laser is demonstrated(12). AgGaS2 is transparent from 0.53 to 12 µm. Although nonlinear optical coefficient is the lowest among the above mentioned infrared crystals, its high short wavelength transparency edging at 550 nm is used in OPOs(13,14) pumped by Nd:YAG laser; in numerous difference frequency mixing experiments(15,16,17,18) using diode, Ti:Sapphire, Nd:YAG and IR dye lasers covering 3–12 µm range; direct infrared countermeasure systems, and SHG of CO2 laser(19). GaSe has band edges at 0.65 and 18 µm. GaSe has been successfully used for efficient SHG of CO2 laser(21) (up to 9% conversion); for SHG of pulsed CO, CO2 and chemical DF-laser (l = 2.36 µm) radiation(27); upconversion of CO and CO2 laser radiation into the visible range(20); infrared pulses generation via difference frequency mixing of Neodymium and infrared dye laser(22,15) or (F-)-centre laser pulses(25); OPG light generation within 3.5–18 µm(24). It is impossibile to cut crystals for certain phase matching angles because of material structure (cleave along (001) plane) limiting areas of applications. |
![]() Type 1 OPO and SHG tuning curves in ZGP |
![]() Type 1 and Type 2 SHG tuning curves in GaSe |
![]() Type 1 OPO and SHG tuning curves in AGS |
![]() Type 1 OPO and SHG tuning curves in AGSe |